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USA Physics and Chemistry Contests
National Chemistry Olympiad
2010 National Chemistry Olympiad
23
23
Part of
2010 National Chemistry Olympiad
Problems
(1)
2010 USNCO Local #23: Spontaneity
Source:
11/25/2012
What are the signs of
△
H
\triangle{H}
△
H
and
△
S
\triangle{S}
△
S
for a reaction that is spontaneous only at low temperatures?
<
s
p
a
n
c
l
a
s
s
=
′
l
a
t
e
x
−
b
o
l
d
′
>
(
A
)
<
/
s
p
a
n
>
△
H
is positive
,
△
S
is positive
<
s
p
a
n
c
l
a
s
s
=
′
l
a
t
e
x
−
b
o
l
d
′
>
(
B
)
<
/
s
p
a
n
>
△
H
is positive
,
△
S
is negative
<span class='latex-bold'>(A)</span>\ \triangle{H} \text{ is positive}, \triangle{S} \text{ is positive} \qquad<span class='latex-bold'>(B)</span>\ \triangle{H}\text{ is positive}, \triangle{S} \text{ is negative} \qquad
<
s
p
an
c
l
a
ss
=
′
l
a
t
e
x
−
b
o
l
d
′
>
(
A
)
<
/
s
p
an
>
△
H
is positive
,
△
S
is positive
<
s
p
an
c
l
a
ss
=
′
l
a
t
e
x
−
b
o
l
d
′
>
(
B
)
<
/
s
p
an
>
△
H
is positive
,
△
S
is negative
<
s
p
a
n
c
l
a
s
s
=
′
l
a
t
e
x
−
b
o
l
d
′
>
(
C
)
<
/
s
p
a
n
>
△
H
is negative
,
△
S
is negative
<
s
p
a
n
c
l
a
s
s
=
′
l
a
t
e
x
−
b
o
l
d
′
>
(
D
)
<
/
s
p
a
n
>
△
H
is negative
,
△
S
is positive
<span class='latex-bold'>(C)</span>\ \triangle{H} \text{ is negative}, \triangle{S} \text{ is negative} \qquad<span class='latex-bold'>(D)</span>\ \triangle{H} \text{ is negative}, \triangle{S} \text{ is positive} \qquad
<
s
p
an
c
l
a
ss
=
′
l
a
t
e
x
−
b
o
l
d
′
>
(
C
)
<
/
s
p
an
>
△
H
is negative
,
△
S
is negative
<
s
p
an
c
l
a
ss
=
′
l
a
t
e
x
−
b
o
l
d
′
>
(
D
)
<
/
s
p
an
>
△
H
is negative
,
△
S
is positive